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The Covalent Model · Paper 2 — Free Chemistry HL Practice Questions

1MasterySAQ-SPolar vs non-polar covalent bonds5 marksPaper 2~8 min
Methane (CH4\text{CH}_4) and chloroform (CHCl3\text{CHCl}_3) are both covalent compounds. Electronegativity values: C=2.5\text{C} = 2.5, H=2.2\text{H} = 2.2, Cl=3.2\text{Cl} = 3.2.
(a)
State the electronegativity difference for a C–Cl bond. [1 mark]
(b)
Both CH4\text{CH}_4 and CHCl3\text{CHCl}_3 have tetrahedral molecular geometry. Explain why CH4\text{CH}_4 is non-polar overall while CHCl3\text{CHCl}_3 is polar overall. [2 marks]
(c)
The experimental dipole moment of CHCl3\text{CHCl}_3 is 1.04 D1.04\,\text{D}. The theoretical dipole moment for a fully ionic C+Cl−\text{C}^+\text{Cl}^- bond of the same bond length is 11.2 D11.2\,\text{D}. Calculate the percentage ionic character of the C–Cl bond in CHCl3\text{CHCl}_3. [2 marks]
diagram

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