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Counting Particles by Mass: The Mole · Paper 2 — Free Chemistry HL Practice Questions

1ChallengeSAQ-LDefinition of the mole and Avogadro's constant10 marksPaper 2~15 min

Data

M(Ti)=47.9 g mol−1M(\text{Ti}) = 47.9\,\text{g mol}^{-1}, M(O)=16.0 g mol−1M(\text{O}) = 16.0\,\text{g mol}^{-1}, NA=6.02×1023 mol−1N_A = 6.02 \times 10^{23}\,\text{mol}^{-1}
A sample of pure titanium(IV) oxide, TiO2\text{TiO}_2, used as a white pigment in paint, has a mass of 7.99 g7.99\,\text{g}.
(a)
Show that the molar mass of TiO2\text{TiO}_2 is 79.9 g mol−179.9\,\text{g mol}^{-1}, and hence determine the number of moles of TiO2\text{TiO}_2 in the 7.99 g7.99\,\text{g} sample. [2 marks]
(b)
Calculate the number of titanium atoms in the 7.99 g7.99\,\text{g} sample of TiO2\text{TiO}_2. [2 marks]
(c)
The mole is described as a "bridge" between the atomic scale and the macroscopic scale. Using the relationship between the mass of one TiO2\text{TiO}_2 formula unit in atomic mass units and the molar mass of TiO2\text{TiO}_2 in grams, explain what this bridging role means and why it is necessary for quantitative chemistry. [3 marks]
(d)
A student claims that a 7.99 g7.99\,\text{g} sample of pure titanium metal contains more atoms than the 7.99 g7.99\,\text{g} sample of TiO2\text{TiO}_2. Evaluate this claim using calculations, and explain why any difference arises in terms of molar mass. [3 marks]

Solutions

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