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The Covalent Model · Paper 2 — Free Chemistry SL Practice Questions

1MasterySAQ-SPolar vs non-polar covalent bonds5 marksPaper 2~8 min
A student investigates the solubility of tetrachloromethane (CCl4\text{CCl}_4) and trichloromethane (CHCl3\text{CHCl}_3) in water. The student predicts that CCl4\text{CCl}_4 will be insoluble in water, while CHCl3\text{CHCl}_3 will show some solubility. Electronegativity values: χ(H)=2.20\chi(\text{H}) = 2.20, χ(C)=2.55\chi(\text{C}) = 2.55, χ(Cl)=3.16\chi(\text{Cl}) = 3.16, χ(O)=3.44\chi(\text{O}) = 3.44
(a)
State why the C-Cl\text{C{-}Cl} bond is polar, and explain why the CCl4\text{CCl}_4 molecule has no net dipole moment. [2 marks]
(b)
Deduce why CHCl3\text{CHCl}_3 has a net dipole moment, whereas CCl4\text{CCl}_4 does not. [2 marks]
(c)
Explain why CHCl3\text{CHCl}_3 shows greater solubility in water than CCl4\text{CCl}_4. [1 mark]
diagram

Solutions

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