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Counting Particles by Mass: The Mole · Paper 2 — Free Chemistry SL Practice Questions

1ChallengeSAQ-LMolar mass and its calculation20 marksPaper 2~30 min
A student investigates the composition of hydrated magnesium sulfate, MgSO4⋅nH2O\text{MgSO}_4 \cdot n\text{H}_2\text{O}. The student places a clean, dry crucible on a balance and records a mass of 18.24 g18.24\,\text{g}. A sample of the hydrated salt is added and the new mass recorded as 28.76 g28.76\,\text{g}. The crucible and contents are heated strongly for several minutes to drive off all water of crystallisation, then cooled in a desiccator. The final mass of the crucible and anhydrous salt is 23.54 g23.54\,\text{g}. M(MgSO4)=120.4 g mol−1M(H2O)=18.02 g mol−1M(\text{MgSO}_4) = 120.4\,\text{g\,mol}^{-1} \qquad M(\text{H}_2\text{O}) = 18.02\,\text{g\,mol}^{-1}
(a)
Calculate the number of moles of water of crystallisation lost and the number of moles of anhydrous MgSO4\text{MgSO}_4 remaining. Hence determine the value of nn in MgSO4⋅nH2O\text{MgSO}_4 \cdot n\text{H}_2\text{O}. [5 marks]
(b)
Explain why the student cooled the crucible in a desiccator rather than on the laboratory bench. [2 marks]
(c)
The student's calculated value of nn is 6.66.6. Evaluate whether this result supports the accepted formula MgSO4⋅7H2O\text{MgSO}_4 \cdot 7\text{H}_2\text{O}, and identify one source of systematic error that could account for the discrepancy. [2 marks]
(d)
State one specific modification to the procedure that would improve the reliability of the value of nn obtained, and explain how it achieves this. [2] Total: [11 marks]
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