Collision Theory and activation energy
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Collision Theory and activation energy — Free MYP5 Chemistry Practice Questions

1QuestionConditions for successful collisions (energy + orientation)Concept Practice
3 marks~5 minCriterion A
The reaction profile below shows energy changes for a reaction proceeding with and without a catalyst.
a
Explain what a catalyst does to the reaction pathway that results in a lower activation energy. [1]
b
Explain, using collision theory, what condition must be met for a collision between reactant particles to be successful. [1]
c
Analyse how the lower activation energy of the catalysed pathway affects the proportion of successful collisions among reactant particles. [1]
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Solutions

2QuestionBasics of Collision TheoryAssessment Practice
3 marks~5 minCriterion C
Two experiments investigate the effect of particle size on the rate of reaction between calcium carbonate and dilute hydrochloric acid.

Experiment 1: A 10 g lump of calcium carbonate is added to 50 cm³ of 1.0 mol dm⁻³ hydrochloric acid at 25°C.

Experiment 2: 10 g of powdered calcium carbonate is added to 50 cm³ of 1.0 mol dm⁻³ hydrochloric acid at 25°C.

The volume of carbon dioxide produced is recorded over time.
a
Explain, using collision theory, why powdered calcium carbonate reacts faster than the lump. [2]
b
A student claims that increasing the concentration of hydrochloric acid would increase the rate more than raising the temperature by 10°C. Evaluate this claim. [1]
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Solutions

3QuestionEffect of activation energy on reaction rateAssessment Practice
5 marks~8 minCriterion B
A student investigates how activation energy affects the rate of decomposition of H2O2(aq)\text{H}_2\text{O}_2\text{(aq)}, using five different catalysts. Oxygen gas production is measured at constant temperature.

ReactionABCDE
Activation energy (kJ/mol)4055705085
Initial rate (mL/s)8.23.51.12.00.4
a
Deduce the relationship between activation energy and initial rate of reaction. [1]
b
Explain this relationship using collision theory. [2]
c
Identify the anomalous data point and justify why it does not fit the expected trend, using collision theory in your answer. [2]
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Solutions

4QuestionBasics of Collision TheoryAssessment Practice
5 marks~8 minCriterion D
Catalytic converters use platinum and palladium to reduce the activation energy of reactions that convert toxic exhaust gases into less harmful substances. Without a catalyst, these reactions proceed too slowly at typical exhaust temperatures (approximately 300–600 °C).
a
Explain how reducing activation energy allows the conversion of COCO and NOxNO_x into CO2CO_2 and N2N_2 to proceed efficiently at exhaust temperatures. [2]
b
Explain how the catalyst provides an alternative reaction pathway to achieve this lower activation energy. [1]
c
Analyse one environmental advantage and one environmental disadvantage of catalytic converters, considering both the reduction of exhaust emissions and the extraction of platinum-group metals. [2]
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