Endothermic and Exothermic reactons
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Endothermic and Exothermic reactons — Free MYP5 Chemistry Practice Questions

1QuestionEnergy transfer between system and surroundingsConcept Practice
2 marks~3 minCriterion A
A student dissolves ammonium nitrate in water inside a beaker. The thermometer reads 15∘C15^\circ\text{C}, while the surrounding air is at 25∘C25^\circ\text{C}. The beaker feels cold to the touch, and arrows on the diagram show energy transferring from the surroundings into the reaction mixture.
a
Deduce the direction of energy transfer between the surroundings and the reaction mixture. [1]
b
Justify the classification of this reaction as endothermic, using the temperature data provided. [1]
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2QuestionTemperature changes during reactionsAssessment Practice
5 marks~8 minCriterion B
A student adds 1.0 g samples of five metals to 50 cm³ of 1.0 mol/dm³ hydrochloric acid in a polystyrene cup, recording the maximum temperature change (ΔT\Delta T) for each:

Metalmagnesiumzincironcoppersilver
ΔT\Delta T (°C)+24.5+12.0+5.50.00.0


An unknown metal X, tested under identical conditions, gives ΔT=+8.5\Delta T = +8.5 °C.
a
State the type of energy change occurring when a reactive metal is added to hydrochloric acid, and write the general word equation for the reaction. [1]
b
Explain how the data above show a relationship between a metal's reactivity and its observed ΔT\Delta T, referring to at least three metals in your answer. [2]
c
Deduce the identity of metal X. Justify your answer using both the ΔT\Delta T data and the reactivity series. [2]
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3QuestionDefinition of endothermic vs exothermic reactionsAssessment Practice
5 marks~8 minCriterion C
A student mixes 50 cm³ of 1.0 mol dm⁻³ HCl with 50 cm³ of 1.0 mol dm⁻³ NaOH in a polystyrene cup and records the temperature every 30 seconds.

Time (s)0306090120150180210240270300
Temperature (°C)22.026.529.831.231.531.030.229.128.027.026.2
a
State whether the reaction is endothermic or exothermic. Give one piece of evidence from the data to support your answer. [1]
b
Explain the shape of the temperature–time graph between 0 s and 120 s, and between 120 s and 300 s. [2]
c
Analyse why the temperature decrease after 120 s does not indicate an endothermic process, and evaluate what this means for using temperature change alone to classify a reaction. [2]
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4QuestionEnergy transfer between system and surroundingsAssessment Practice
6 marks~9 minCriterion D
Single-use hand warmers contain iron powder, water, salt, and activated carbon. When exposed to air, the iron undergoes oxidation:

4Fe(s)+3O2(g)→2Fe2O3(s)4\text{Fe}(s) + 3\text{O}_2(g) \rightarrow 2\text{Fe}_2\text{O}_3(s)

The reaction releases thermal energy, raising the surface temperature of the warmer to approximately 50–60 °C. Millions of hand warmers are discarded globally each year.
a
Explain why this reaction is classified as exothermic, and describe the energy transfer that occurs between the hand warmer (system) and its surroundings. [2]
b
Explain how two different properties of the materials used in hand warmers contribute to environmental concerns when the warmers are disposed of at large scale. [2]
c
Analyse the health risk posed by the surface temperature of the hand warmer during use, and evaluate the effectiveness of one method to reduce this risk. [2]
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Solutions

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