A metal tip in a scanning tunnelling microscope (STM) is held at distance d from a conducting surface. Electrons in the metal have total energy E less than the barrier height V0 at the tip–surface gap.
(a)
Analyse the phenomenon of quantum tunnelling as evidence for the wave nature of particles, and evaluate how the STM exploits this phenomenon to achieve atomic-scale resolution.
In your answer:
- explain why classical mechanics predicts zero transmission probability for a particle with E<V0
- explain how the quantum wavefunction gives a non-zero transmission probability through a barrier of finite width d
- describe the role of the de Broglie wavelength and the exponential decay constant α=2m(V0−E)/ℏ inside the barrier
- evaluate how the exponential dependence of tunnelling current on tip–surface separation enables atomic-scale vertical resolution [6 marks]
(b)
The tip is held at d=0.50nm from the surface. The barrier height above the electron energy is U=V0−E=1.0eV.
(i) Calculate the decay constant α, where α=2meU/ℏ. [2 marks]
(ii) The tip is retracted to d=0.60nm. Using T∝e−2αd, calculate the ratio T2/T1 of the tunnelling probability at d=0.60nm to that d=0.50nm. [2 marks]
(iii) Evaluate what the result of (b)(ii) implies about the ability of the STM to resolve individual atoms separated by 0.10nm vertically. [2 marks]