Isotopes and Relative Atomic Mass
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Isotopes and Relative Atomic Mass — Free MYP4 Chemistry Practice Questions

1QuestionDefinition and Examples of IsotopesConcept Practice
2 marks~3 minCriterion A
Iodine-123 (123^{123}I) is a radioactive isotope used in hospitals to image a patient's thyroid gland. A small quantity is administered to the patient, and its gamma emissions are detected to produce a diagnostic image.
a
Outline what makes 123^{123}I an isotope of iodine. [1]
b
A patient undergoing this procedure expresses concern about radiation exposure. Discuss one limitation of using 123^{123}I for thyroid imaging that is directly related to this concern. [1]
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Solutions

2QuestionDefinition and Examples of IsotopesAssessment Practice
5 marks~8 minCriterion C
Mass spectrometry of a chlorine sample produces two peaks:

m/z=35m/z = 35, relative abundance =75.8%= 75.8\%
m/z=37m/z = 37, relative abundance =24.2%= 24.2\%

A separate experiment determines the average atomic mass of chlorine to be 35.45 amu35.45 \text{ amu}.

The weighted-average formula for atomic mass is:

average atomic mass=(m1×a1)+(m2×a2)100\text{average atomic mass} = \frac{(m_1 \times a_1) + (m_2 \times a_2)}{100}

where m1m_1, m2m_2 are isotope masses and a1a_1, a2a_2 are their percentage abundances.
a
Calculate the average atomic mass of chlorine predicted by the two-isotope data. [2]
b
Deduce whether the experimentally determined value of 35.45 amu35.45 \text{ amu} is consistent with chlorine existing as only two stable isotopes. Justify your reasoning using your answer to part (a) and the concept of experimental error. [3]
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3QuestionCalculating Relative Atomic Mass RAMAssessment Practice
6 marks~9 minCriterion D
A nuclear accident releases iodine-131 into a local water supply. Natural iodine consists entirely of iodine-127 (mass = 126.9045 u). A contaminated water sample contains 80% iodine-127 and 20% iodine-131 (mass = 130.9061 u) by number of atoms.
a
Calculate the relative atomic mass (RAM) of iodine in the contaminated sample. [2]
b
Deduce whether the altered RAM alone is sufficient to confirm the presence of iodine-131 contamination. Justify your reasoning with reference to the standard RAM of iodine. [2]
c
Evaluate the limitations of using RAM as a monitoring tool for iodine-131 contamination, with reference to the health risks posed by iodine-131 accumulation in the thyroid gland. [2]
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4QuestionStability of Isotopes and Radioactivity IntroAssessment Practice
4 marks~6 minCriterion B
The stability of an isotope depends on its neutron-to-proton ratio (n/pn/p). Data for five isotopes are given below.

IsotopeH-1H-2He-4C-14U-238
Protons112692
Neutrons0128146
n/pn/p ratio0.001.001.001.331.59
Stabilitystablestablestableradioactiveradioactive
a
Describe the relationship between the n/pn/p ratio and isotope stability, referring to specific values in the data above. [2]
b
Deduce whether oxygen-16 (8 protons, 8 neutrons) and oxygen-18 (8 protons, 10 neutrons) are stable or radioactive. Justify each prediction using the pattern from part (a). [2]

Solutions

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