Energy Profiles and Bond Theory
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Energy Profiles and Bond Theory — Free MYP4 Chemistry Practice Questions

1QuestionEnergy profile diagrams (reactants → products)Concept Practice
2 marks~3 minCriterion A
The energy profile diagram below shows a chemical reaction. The vertical axis represents potential energy and the horizontal axis represents progress of the reaction. A curved line rises from the reactants on the left to a peak, then falls to the products on the right. An arrow is drawn vertically from the reactants' energy level to the peak of the curve.
a
Identify what the arrow in the diagram represents. [1]
b
Explain why this quantity is essential for the forward reaction to occur. [1]
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Solutions

2QuestionInterpreting energy diagrams (peaks, energy levels)Assessment Practice
3 marks~5 minCriterion C
Disposable hand warmers use the oxidation of iron: 4Fe+3O2→2Fe2O34\text{Fe} + 3\text{O}_2 \rightarrow 2\text{Fe}_2\text{O}_3. The energy profile for this reaction is shown below.
a
Interpret the energy profile to explain why the hand warmer releases heat to the user's hands. [2]
b
A student claims that used hand warmers can simply be thrown in general waste without environmental consequence. Evaluate this claim, referring to one specific environmental impact of disposal. [1]
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Solutions

3QuestionEnergy profile diagrams (reactants → products)Assessment Practice
5 marks~8 minCriterion D
The Haber-Bosch process synthesises ammonia at 400–500°C and 200 atm, consuming large quantities of fossil fuel energy. A low-temperature alternative operates at 150°C and 10 atm using a toxic catalyst. The energy profile diagram shows two curves (A: Haber-Bosch; B: catalytic) starting at the same reactant energy level and ending at the same product energy level, with Curve A reaching a significantly higher peak than Curve B.
a
On the energy profile diagram, label the activation energy EaE_a for each process. [1]
b
Analyse how the energy profiles of the two processes account for the difference in their environmental carbon footprints. [2]
c
Evaluate the trade-offs between the environmental benefit and the health and safety risks introduced by using the toxic catalyst in the low-temperature process. [2]
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Solutions

4QuestionActivation energy and overall energy change (ΔH – qualitative)Assessment Practice
3 marks~5 minCriterion B
The table below shows activation energy (EaE_a) and overall energy change (ΔH\Delta H) for four reactions.

ReactionEaE_a (kJ mol−1^{-1})ΔH\Delta H (kJ mol−1^{-1})
Combustion of methane265−890
Decomposition of hydrogen peroxide75−98
Rusting of iron165−1640
Photosynthesislight-driven+2800
a
Deduce the relationship between EaE_a and whether a reaction is exothermic or endothermic, using the data to support your answer. [1]
b
Explain how the relative energy levels of reactants and products differ between exothermic and endothermic reactions. [1]
c
Photosynthesis has a positive ΔH\Delta H yet requires light rather than a conventional activation energy. Analyse what this suggests about the role of EaE_a in determining the energy stored in the products of a reaction. [1]

Solutions

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