Introduction to Organic Compounds
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Introduction to Organic Compounds — Free MYP5 Chemistry Practice Questions

1QuestionCovalent bonding in organic moleculesConcept Practice
3 marks~5 minCriterion A
The graph below shows the boiling points of four straight-chain alkanes: methane (CH4\text{CH}_4), ethane (C2H6\text{C}_2\text{H}_6), propane (C3H8\text{C}_3\text{H}_8), and butane (C4H10\text{C}_4\text{H}_{10}).
a
State the trend in boiling point as the number of carbon atoms increases from methane to butane. [1]
b
Identify the type of intermolecular force responsible for this trend. [1]
c
Explain why longer carbon chains produce stronger intermolecular forces, resulting in higher boiling points. [1]
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Solutions

2QuestionOrganic vs inorganic compounds (comparison)Assessment Practice
3 marks~5 minCriterion D
A student investigates the environmental persistence of two pesticides: DDT (C14H9Cl5\text{C}_{14}\text{H}_9\text{Cl}_5), an organic compound, and copper sulfate (CuSO4\text{CuSO}_4), an inorganic salt. Each is dissolved in a separate 1.0 L1.0\ \text{L} water sample at an initial concentration of 1.0 g/L1.0\ \text{g/L}. After 30 days under controlled conditions (25°C25°\text{C}, constant light, aeration), the concentrations measured are:

DDT: 0.95 g/L0.95\ \text{g/L}
Copper sulfate: 0.50 g/L0.50\ \text{g/L}
a
Deduce which pesticide is more persistent, using quantitative evidence from the data. [1]
b
Discuss TWO limitations of this experiment that may prevent the results from accurately predicting the ecological impact of these pesticides in a real river ecosystem. In your discussion, refer to the organic or inorganic nature of each pesticide. [2]
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Solutions

3QuestionTetravalency of carbon/ CatenationAssessment Practice
5 marks~8 minCriterion B
The table below shows data for four organic compounds.

Compound — Molecular formula — C–C bond length (pm) — C–C bond enthalpy (kJ/mol)

Methane — CH4CH_4 — 154 — 348

Ethene — C2H4C_2H_4 — 134 — 612

Ethyne — C2H2C_2H_2 — 120 — 837

Benzene — C6H6C_6H_6 — 140 — 518
a
State the relationship between C–C bond length and bond enthalpy shown by methane, ethene, and ethyne. [1]
b
Using the data, deduce why benzene's bond length (140 pm) and bond enthalpy (518 kJ/mol) are anomalous compared to the pattern in (a). [2]
c
Analyse whether benzene violates the tetravalency rule, using the concept of delocalized electrons to support your reasoning. [2]
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Solutions

4QuestionSaturated vs unsaturated compoundsAssessment Practice
5 marks~8 minCriterion C
A student tests four liquid samples — W, X, Y, and Z — with bromine water to investigate saturation. Decolorization times are recorded:

Sample W: no decolorization after 120 s
Sample X: decolorizes in 15 s
Sample Y: no decolorization after 120 s
Sample Z: decolorizes in 18 s

W is hexane (saturated), X is hex-1-ene (unsaturated), and Y is cyclohexane (saturated). Z is unknown.

A hypothesis states: "Sample Z contains a carbon–carbon double bond."
a
State what is observed when bromine water reacts with a compound containing a C=CC{=}C bond, and identify the type of reaction occurring. [1]
b
Using the data from W, X, and Y, explain why bromine water is a reliable test for distinguishing saturated from unsaturated compounds. [2]
c
Evaluate the hypothesis using all four samples' data, identifying one limitation of this conclusion. [2]
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Solutions

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